(Croconato-κ2 O,O′)bis(1,10-phenanthroline-κ2 N,N′)zinc(II)
نویسندگان
چکیده
In the title compound, [Zn(C(5)O(5))(C(12)H(8)N(2))(2)], the Zn atom is in a slightly distorted octa-hedral environment. The mol-ecule lies across a twofold rotation axis, around which two 1,10-phenanthroline ligands are arranged. There are short contacts between the 1,10-phenanthroline groups and the O atoms of the croconate ligand, which probably stabilize the crystal structure via weak C-H⋯O interactions.
منابع مشابه
(5,5′-Dicarboxybiphenyl-2,2′-dicarboxylato-κ2 O 2,O 2′)bis(1,10-phenanthroline-κ2 N,N′)zinc(II) dihydrate
In the title compound, [Zn(C(16)H(8)O(8))(C(12)H(8)N(2))(2)]·2H(2)O, the Zn(II) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from a 5,5'-dicarboxy-biphenyl-2,2'-dicarboxyl-ate ligand and four N atoms from two 1,10-phenanthroline mol-ecules in a distorted octa-hedral geometry. The crystal structure involves O-H⋯O hydrogen bonds.
متن کامل(Heptanedioato-κ2 O,O′)bis(1,10-phenanthroline-κ2 N,N′)zinc(II) hexahydrate
In the crystal structure of the title compound, [Zn(C(7)H(10)O(4))(C(12)H(8)N(2))(2)]·6H(2)O, the Zn(II) atom is coordinated by two carboxyl-ate O atoms of a mono-bidentate chelating pimelate anion (pimelic acid is hepta-nedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octa-hedral ZnN(4)O(2) coordination geometry. The complexes are assembled into a ...
متن کامل(Croconato-κ2 O,O′)bis(1,10-phenanthroline-κ2 N,N′)manganese(II)
The title complex, [Mn(C(5)O(5))(C(12)H(8)N(2))(2)], lies across a crystallographic twofold axis which passes through the Mn atom and bisects the croconate ligand. The two 1,10-phenanthroline (phen) ligands are arranged in a propeller manner and the local mol-ecular geometry of the MnN(4)O(2) unit is severely distorted octa-hedral. This may be inter-preted as a structural perturbation of the Mn...
متن کاملPoly[[(1,10-phenanthroline-κ2 N,N′)zinc]-μ-2,5-bis(allyloxy)terephthalato-κ2 O 1:O 4]
The title compound, [Zn(C(14)H(12)O(6))(C(12)H(8)N(2))](n), is a coordination polymer forming one-dimensional infinite zigzag chains along [10[Formula: see text]] by inter-connection of Zn(II) atoms by 2,5-bis-(all-yl-oxy)-terephthalate anions via the carboxyl-ate groups. The Zn(II) atom is located on a twofold axis and is in a distorted tetra-hedral coordination formed by the two carboxyl-ate ...
متن کاملBis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2 O 2:O 6)bis[bis(1,10-phenanthroline-κ2 N,N′)cobalt(II)] dimethylformamide disolvate
The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octa-hedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2',3'-d]thio-phene-2,6-dicarb-oxy-l-ate...
متن کامل